10.2190/91VQ-HN0E-M2BJ-58UP 91VQHN0EM2BJ58UP 4 Physical-Chemical Treatment of Acid Mine Water from a Superfund Site 237 263 20020509 20020509 20020509 20020509 91VQHN0EM2BJ58UP.pdf http://baywood.metapress.com/link.asp?target=contribution&id=91VQHN0EM2BJ58UP 3 Marcia H. Bates John N. Veenstra John Barber Raju Bernard Julie Karleskint Parweiz Khan Raghupathi Pakanti Michael Tate Oklahoma State University, Stillwater, Oklahoma Various physical-chemical treatment methodologies were evaluated for treating over 76,000 acre feet of acid mine water at the Tar Creek Superfund site in Northeastern Oklahoma. Chemical precipitation, chemical precipitation with polymer addition, activated carbon, and ion exchange were used to reduce levels of iron, zinc, cadmium, and lead to acceptable levels. All treatment techniques used were successful, but cost considerations eliminated ion exchange and activated carbon as viable options.

Oklahoma Water Resources Board, Tar Creek Field Investigation Task 1.1, Effects of Acid Mine Drainage on the Surface Water Resources in the Tar Creek Area, Ottawa County, Oklahoma, EPA Grant No. CX 810192-010, 1983.

J. S. Whang, et al., Soluble-Sulfide Precipitation for Heavy Metals from Wastewaters, Environ. Prog., 1, p. 110, 1982.

K. A. Brantner and E. J. Cichon, Heavy Metals Removal: Comparison of Alternate Precipitation Processes, Proceedings of the 13th Mid-Atlantic Industrial Waste Conference, 51, 1988.

K. Jurkiewicz, Studies on the Separation of Cadmium from Solutions by Foam Separation II. Precipitate Flotation of Cadmium Hydroxide, Sep. Sci. Technol., 19, p. 1051, 1985.

J. P. Gould, et al., Factors Influencing Zinc Cementation of Cadmium, Proceedings of the Environmental Engineering Division Special Conference, American Society of Civil Engineers, p. 366, 1985.

D. Grosse, et al., Treatment of Aqueous Metal Bearing Hazardous Wastes, 8th AESF/EPA Conference on Pollution Control in the Metallic Finishing Industry, American Electroplaters and Surfacers Society, 1987.

A. DuPont, Lime Treatment of Liquid Waste Containing Heavy Metals, Pollution Engineering, 19:4, p. 84, 1987.

T. Nishimura and K. Tozawa, Removal of Arsenic from Waste Water by Addition of Calcium Hydroxide and Stabilization of Arsenic-Bearing Precipitates by Calcination, Impurity Control Disposal, Proceedings of the 15th CIM Annual Hydrometallurgists Meeting (G. B.), 15, p. 1, 1985.

J. Teringo III, Magnesium Hydroxide Reduces Sludge/Improves Filtering, Pollution Engineering, 19:4, p. 78, 1987.

G. S. Logsdon and J. M. Symons, Mercury Removal by Conventional Water Treatment Techniques, JAWWA, 15, p. 554, 1972.

M. D. Pandey and M. Chauduri, Removal of Inorganic Mercury from Water by Bitumas Coal, Water Research, 16, p. 1113, 1982.

M. I. Humenick and J. L. Schnoor, Improving Mercury (II) Removal by Activated Carbon, Journal of Environmental Engineering Division, Proceedings of the American Society of Civil Engineers, 100, p. 1249, 1974.

L. Thiem, et al., Removal of Mercury from Drinking Water Using Activated Carbon, JAWWA, 68, p. 447, 1971.

C. P. Huang and P. K. Wirth, Activated Carbon for Treatment of Cadmium Wastewater, Journal of Environmental Engineering Division, Proceedings of the American Society of Civil Engineers, 107, p. 1280, 1982.

M. O. Corapcioglu and C. P. Huang, The Adsorption of Heavy Metals on Hydrous Activated Carbon, Water Research, 21, p. 1031, 1987.

H. Koshima and H. Orishi, Adsorption of Metal Ions on Activated Carbon from Aqueous Solutions at pH 1-13, Talanta, 33:5, p. 391, 1986.

Y. Ku and R. W. Peters, Innovative Uses for Carbon Adsorption of Heavy Metals from Plating Wastewaters, I. AC Polishing Treatment, Environmental Progress, 6, p. 119, 1987.

C. W. Greer and A. L. Huber, Synthetic Compositions: Effective Treatment of Heavy Metal Containing Wastewaters from the Metal Finishing Industry, 74th Annual AESF Technical Conference, Proceedings of the American Electroplaters and Surfacer Finishers Society, 1987.

W. H. Waitz, Ion Exchange in Heavy Metals Removal and Recovery, Publication No. 162, Rohm and Haas Company, Fluid Process Chemicals Department, Philadelphia, Pennsylvania, 1979.

A. K. Shcheglov and L. D. Sedova, Ion-Exchange Purification of Sewage for Copper Salt Removal, Prib. Sist. Upr., 1, p. 38, 1986.

O. P. Mathur, et al., Removal of Cyanide and Heavy Metals from Industrial Effluent Using Insoluble Functionalized Polysaccharide Derivatives, Bull. Electrochem., 2:2, p. 141, 1986.

M. C. Loizidou, Heavy Metal Removal Using Natural Zeolites, Heavy Metal Environ. International Conference 15th, 1, p. 649, 1985.

American Public Health, Standard Methods for the Examination of Water and Wastewater, 15th Edition, APHA, Washington, D. C., 1980.

Hach Chemical Company, Hach Water Analysis Handbook, Hach Company, Loveland, Colorado, 1982.

Oklahoma Water Resources Board, Water Quality Standards, Publication III, Oklahoma City, Oklahoma, 1982.

N. L. Nemerow, Scientific Stream Pollution Analyses, McGraw-Hill Book Company, New York, 1974.

W. J. Weber, Physiochemical Processes for Water Quality Control, Wiley Interscience, New York, 1972.

L. D. Benefield, J. F. Judkins, and B. L. Weand, Process Chemistry for Water and Wastewater Treatment, Prentice Hall, Englewood Cliffs, New Jersey, 1982.

R. S. Summers and P. V. Roberts, Simulation of DOC Removal in Activated Carbon Beds, Journal of the Environmental Engineering Division, ASCE, 110:1, pp. 73-92, 1984.

H. S. Harned and R. M. Hudson, The Diffusion Coefficient of Zinc Sulfate in Dilute Aqueous Solution at 25°, Journal of the American Chemical Society, 73:8, pp. 3781-3783, 1951.

C. N. Satterfield, Heterogeneous Catalysis in Practice, McGraw-Hill, New York, 1980.

C. N. Satterfield, Mass Transfer in Heterogeneous Catalysis, MIT Press, Cambridge, Massachusetts, 1970.

T. Vermeulen, Separation by Adsorption Methods, in Advances in Chemical Engineering, Volume II, T. B. Drew and J. W. Hoopes (eds.), Academic Press, New York, 1958.

N. Wakao and T. Funazkri, Effect of Fluid-Dispersion Coefficients on Particle-to-Fluid Mass Transfer Coefficients in Packed Beds, Chemical Engineering Science, 33, pp. 1375-1384, 1978.

G. A. Guter, Removal of Nitrate from Contaminated Water Supplies for Public Use: Final Report, EPA 600/2-82-042 Municipal Environmental Research Lab., Cincinnati, Ohio, 1982.